Grounds for Greener Chemistry
A huge portion of the world’s economy depends on decades-old chemical processes that are expensive, energy-intensive and harmful to the environment. One of the most important challenges facing scientists today is developing new, “green” processes that achieve the same goals but are more environmentally and economically sustainable. Thus, researchers are searching for natural, nontoxic, inexpensive and readily available sources of useful chemicals.
Chemistry researcher Niny Z. Rao, PhD, and physics researcher Brian Yust, PhD, have demonstrated the utility of one such source: used coffee grounds. “Coffee has great potential as a component in green chemistry,” explains Dr. Rao, who has studied the chemistry of coffee for more than a decade. “Even spent coffee grounds contain bountiful amounts of antioxidants and other naturally occurring chemicals.”
In particular, their research has shown that spent coffee grounds can drive the process of creating gold and silver nanoparticles. “Nanoparticles are ultra-fine materials with unique properties, and they are essential to innovative technologies ranging from improved food packaging to advanced medical imaging,” says Dr. Yust. “Unfortunately, standard processes for synthesizing nanoparticles can require hazardous chemicals and create toxic waste by-products.”
The scientists knew that spent coffee grounds contain antioxidants, which are great “scavengers” and attach themselves to certain other molecules. One of the most important antioxidants is chlorogenic acid, which can catalyze the nano-crystallization of gold or silver atoms in a solution. “Therefore, we hypothesized that combining coffee’s natural chemicals with some gold and silver would prompt a nanoparticle crystallization process,” Dr. Rao says.
They found that even relatively small amounts of spent coffee grounds — regardless of roast or initial brew method — could be used to create a variety of shapes and sizes of the nanoparticles without using corrosive chemicals or energy-intensive processing. While other research groups have explored using fresh ground coffee or newly brewed coffee to create nanoparticles, Drs. Rao and Yust have demonstrated the potential to use as little as two grams of spent coffee grounds to drive a sustainable nanoparticle synthesis process.
In the current chemistry-focused phase of the ongoing project, Dr. Rao says, “We are learning about the utility of different coffee varieties and brewing methods for creating different chemical catalysts. We’re also exploring the specific role of active antioxidants present in the coffee extract, and how the full range of chemicals in spent coffee grounds can be used for other nano-chemistry purposes.”
On the physics side, Dr. Yust explains, “We’re exploring the effect that specific chemical constituents in the extracts have on the final size and shape of nanoparticles. Having fine control over these effects should enable us to create nanoparticles of specific dimensions and structures, such as the gold nanorod shapes that are used in a number of medical applications.”